工业废水去除重金属技术的研究现状与进展
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1.中国地质科学院水文地质环境地质研究所;2.河北省/中国地质调查局地下水污染机理与修复重点实验室;3.中国地质大学(北京);4.华北水利水电大学

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Research status and new development on heavy metals removal from industrial wastewater
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1.The Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geosciences;2.Key Laboratory of Groundwater Remediation of Hebei Province and China Geological Survey;3.China University of Geosciences(Beijing);4.North China University of Water Resources and Electric Power

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    摘要:

    【研究目的】随着工业的快速发展,重金属(如砷、铜、铬、镉、镍、锌、铅、汞和锰)废水的排放量逐渐增加。由于其不可生物降解且半衰期较长,废水中的重金属会导致地下水、地表水、土壤和农作物受到严重污染,危害人体和动植物的健康。因此需要从工业废水中去除这些有毒重金属。【研究方法】基于现阶段的污染现状,综合考虑去除效率、处理成本、污泥量、可回收性等因素,分析工业废水中重金属的治理现状与进展。【研究结果】本文全面地介绍了有效去除工业废水中重金属的主要技术,总结了各技术的内在机理、影响因素(pH、温度和重金属浓度等)及各自优缺点,并对重金属去除技术的发展趋势进行了展望,以期为其综合治理提供有意义的参考。【结论】各种去除技术均有广泛的应用空间,但同时也存在着诸多缺陷,常规的物理化学方法存在着污泥量高、去除效率低和能耗高等问题,而生物方法对pH值和温度依赖性强、能量和维护需求高。组合工艺是提高重金属分离效率的一种可行方法。研究和发展新型天然吸附剂、膜技术和生物技术,加强多种技术的综合应用,是治理重金属污染的有效途径。

    Abstract:

    【Objective】With the improvement of industrialization, the discharge of industrial wastewater containing heavy metals (such as arsenic, copper, chromium, cadmium, nickel, zinc, lead, mercury and manganese) is gradually increasing. Due to its non-biodegradability and long half-life, heavy metals in wastewater cause serious pollution in groundwater, surface water, soil and crops, seriously endangering the health of human beings, animals and plants. Therefore, it is necessary to remove these toxic heavy metals from industrial wastewater.【Methods】Based on the current status of heavy metal pollution in industrial wastewater, the current status and progress of heavy metal treatment in industrial wastewater are analyzed by comprehensively considering removal efficiency, treatment cost, sludge output, recyclability and other factors.【Results】This paper presents the research of main technologies on heavy metals removal from industrial wastewater. The internal mechanism, influencing factors (pH, temperature and heavy metal concentration) and their advantages and disadvantages of each technology are summarized, and the development trend of heavy metal removal technology in industrial wastewater is prospected in order to provide meaningful reference for the comprehensive treatment of industrial wastewater containing heavy metals.【Conclusions】Various heavy metal removal technologies have broad prospects on heavy metal treatment, coming with some drawbacks. Conventional physical and chemical methods have problems such as high sludge production, low removal efficiency and high energy consumption, while biological methods have strong dependence on pH and temperature, and high demand for energy and maintenance. Combined process is a feasible method to improve the removal efficiency of heavy metals. Research and development of new natural adsorbents, membrane technology and biotechnology, and strengthening the comprehensive application of various technologies are effective ways to removing heavy metal from industrial wastewater.

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  • 收稿日期:2022-11-28
  • 最后修改日期:2023-01-10
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  • 在线发布日期: 2023-02-06
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