Abstract: Zhangyangou bimodal volcanic rocks are located in Hengxianhe area，Sanchazi-Lueyang segment of Mian-Lue tectonic zone. The bimodal volcanic rocks consist of metamorphosed basic volcanic rocks and metamorphosed acid-intermediate rocks in close association, and the protoliths are sub-alkaline basalt and sub-alkaline rhyolitic-dacite. On account of the higher REE concentrations in basalt than in rhyolitic-dacite, the authors hold that the origin of rhyolitic-dacite was partial melting of the crustal material rather than the fractional crystallization of the basaltic magma. Basic volcanic rocks show the intraplate geochemical characteristics such as high Zr concentrations and Zr/Y ratios, and their marks of arc result from the hybridism of the crustal material. The result of U-Pb isotope dating by means of Laser Ablation Inductively Coupled Plasma Mass Spectrometry makes it clear that the formation age of the rhyolite is (728±10) Ma(n=4, MSWD=0.14). Combined with the regional geological background, the authors consider that Zhangyangou bimodal volcanic rocks were formed in a continental rift environment under the crust extensional mechanism. The formation of Zhangyangou bimodal volcanic rocks heralded the opening of Neoproterozoic Ocean. This new achievement is of important significance both for the further study of the evolution of Mian-Lue tectonic zone and the breakup of Rodinia supercontinent and other continents on the north margin of the Yangtze block.