福建省永定大排铁铅锌多金属矿矿床特征及成矿时代

赵希林; 于胜尧; 余明刚; 姜杨; 刘凯; 毛建仁

福建省永定大排铁铅锌多金属矿矿床特征及成矿时代

1. 中国地质调查局南京地质调查中心, 江苏南京 210016;
2. 中国地质科学院地质研究所, 北京 100037

基金项目:

中国地质调查局基础地质调查项目(12120113070800,1212011085446)资助。

详细信息

作者简介:
赵希林,汉族,男,1980年生,副研究员,矿物学、岩石学、矿床学专业;E-mail:zxl24@126.com或zxlgjm@sina.com.cn。

通讯作者:
于胜尧,汉族,男,1982年生,副研究员,岩石学专业

中图分类号: P618.31;P618.42~43;P597
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出版历程
- 收稿日期: 2014-11-28
- 修回日期: 2015-01-15
- 网络出版日期: 2023-09-25
- 刊出日期: 2016-02-24

Geological characteristics and metallogenic epochs of the Dapai Fe-Pb-Zn polymetallic deposit in Yongding County, Fujian Province

1. Nanjing Center, China Geological Survey, Nanjing 210016, Jiangsu, China;
2. Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037, China

Funds:

Supported by China Geological Survey programs(No. 12120113070800, No. 1212011085446).

摘要

摘要: 福建永定大排铁铅锌多金属矿床是闽西南地区近年来发现的大型多金属矿床。对矿区内蚀变花岗岩的锆石SHRIMP U-Pb定年和辉钼矿Re-Os同位素测年结果显示其分别形成于(127.0±1.8) Ma和(133.5±4.1) Ma,这一年龄与区内马坑铁矿及潘田铁矿的成岩成矿年龄相一致,指示区域上该期铁铅锌多金属矿与区内花岗质岩浆作用有密切的时间和成因联系,大排铁铅锌多金属的主成矿期可能为燕山期。结合已有的区域地质资料及研究成果,认为福建永定大排铁铅锌多金属矿床可能为层控矽卡岩型-斑岩型复合型矿床。
- 大排铁铅锌矿 /
- 锆石SHRIMP U-Pb年龄 /
- 辉钼矿Re-Os等时线年龄 /
- 复合型矿床
Abstract: The Dapai Fe-Pb-Zn polymetallic ore deposit in Yongding County of southwestern Fujian Province is a large-sized polymetallic deposit discovered in recent years. Zircon SHRIMP U-Pb dating of Dapai altered granodiorite is (127±1.8) Ma, equal to the Re-Os isotopic age (133.5±4.1) Ma of the granodiorite porphyry. Both ages are consistent with the age of Makeng and Pantian iron ore deposit in the same area, indicating genetic relation between the granitic magmatism and the Fe-Pb-Zn metallogenesis in the area, with the main metallogenic epoch being Yanshanian. Based on the previous research results and data obtained by the authors, it is inferred that the Dapai Fe-Pb-Zn polymetallic ore deposit belongs to stratabound skarn-porphyry type composite deposit.
- Dapai Fe-Pb-Zn deposit /
- zircon SHRIMP U-Pb age /
- Re-Os isochron age /
- composite deposit

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图 1 福建龙岩地区地质矿产略图^[18]

Figure 1. Geological sketch map of Longyan area in Fujian Province^[18]

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图 2 福建永定大排铜铅锌多金属矿区地质简图

Figure 2. Geological sketch map of Dapai area,Yongding County,Fujian

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图 3 大排矿区蚀变花岗闪长岩及花岗闪长斑岩镜下特征

a—蚀变花岗闪长岩中蚀变矿物特征,黑云母多绿泥石化,长石高岭土化蚀变作用明显; b—蚀变花岗闪长岩中长石的蚀变特征,钾长石表面较“脏”,高岭土化作用明显; c—花岗闪长斑岩结构特征,斑晶为石英和钾长石; d—花岗闪长斑岩的似班状花岗结构,显示巨大的钾长石斑晶,并伴随着高岭土化作用

Figure 3. Microphotographs of altered granodiorite and granodiorite porphyry

a-Characteristics of altered minerals in altered granodiorite,chloritization of biotite and kaolinization of feldspar; b-Characteristics of alteredfeldspars in altered granodiorite,obvious kaolinization of feldspars,with dirty feldspars surface; c- Characteristics of texture of granodioriteporphyry,with the phenocryst being feldspars; d-Porphyritic texture of granodiorite porphyry,K−feldspar megacryst with kaolinization

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图 4 福建永定大排铁铅锌多金属矿A-A’地质剖面图

Figure 4. A-A’geologic section of the Dapai Fe-Pb-Zn deposit,Yongding County,Fujian Province

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图 5 福建永定大排铁铅锌多金属矿矿石矿物显微特征

a—充填交代结构-方铅矿不规则状充填交代脉石矿物; b—同生边结构-方铅矿与闪锌矿相互成生关系为同生边; c—包裹结构-方铅矿包裹脉石; d—固溶体结构-黄铜矿与赋存于其中的肠状闪锌矿呈固溶体; Gn—方铅矿; Spn—闪锌矿; Cp—黄铜矿

Figure 5. Microcharacteristics of ore minerals in the Dapai Fe-Pb-Zn deposit,Yongding County,Fujian Province

a-Infilling and metasomatic structure-galena infilling and replacing gangue minerals; b-Syngenetic marginal texture-galena and sphaleritesyngenetic margin,respectively; c-Wrapping structure-galena wrapping gangue; d-Solid-solution texture-chalcopyrite and enteroid sphaleritecomposing solid-solution; Gn- Galena; Spn- Sphalerite; Cp- Chalcopyrite

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图 6 大排蚀变花岗闪长岩(D82−1)锆石的SHRIMP CL测点位置及U−Pb年龄谐和图

Figure 6. CL images and analytical spots of the zircons and U−Pb concordia diagrams for the Dapai granidiorite

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图 7 大排辉钼矿Re−Os等时线和加权平均年龄图

Figure 7. Re−Os isochron diagram of molybdenite and weight diagram from ores of the Dapai Fe−Pb−Zn deposit

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图 8 大排铁铅锌多金属矿15线地质剖面图

Figure 8. Geological section along No. 15 line of the Dapai Fe−Pb−Zn deposit

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表 1 福建永定大排铁铅锌多金属矿主要矿石类型及其特征

Table 1 Main ore types and characteristics in the Dapai Fe−Pb−Zn deposit

矿石种类	硫化铅锌矿石	磁铁矿石
主要金属矿物	方铅矿、闪锌矿、黄铜矿为主，次为黄铁矿	磁铁矿，少量穆磁铁矿、赤铁矿
伴生金属矿物	局部伴生辉钼矿、磁铁矿、穆磁铁矿、赤铁矿	闪锌矿、黄铜矿、辉钼矿及黄铁矿
脉石矿物	次透辉石、石榴石、绿帘石、锰钙辉石、黑柱石及石英、方解石	石榴石、透辉石、次透辉石、方解石、金云母、绿泥石及石英等
矿石结构	以粒状变晶镶嵌结构、变余凝灰结构、交代充填结构同生边结构、固溶体结构为主，次为半自形粒状结构、他形粒状结构及碎裂结构、包裹结构等(图5)	全自形粒状集合体结构、他形-半自形粒状结构为主，次为交代熔融结构及交代残留结构(图5)
矿石构造	块状(团块状)、条带状、层纹状、浸染状为主，次为细脉状	块状构造、斑杂状构造、浸染状构造、条带状构造、层纹状构造

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表 2 福建永定大排铁铅锌矿床辉石电子探针分析结果

Table 2 Electron microprobe analyses of pyroxenes from Yongding Dapai Fe−Pb−Zn deposit in Fujian Province

样品号	矿物名称	化学组成/%										端员组成/%
样品号	矿物名称	Si0₂	Ti0₂	Al₂O₃	FeO	MnO	MgO	CaO	Na₂0	k₂o	总计	Di	Hed	Jo
Dp5-1	锰钙辉石	49.58	0.00	0.23	8.16	16.97	1.50	22.57	0.20	0.00	99.21	9.5	29.1	61.3
Dp5-2	锰钙辉石	49.79	0.00	0.24	7.77	17.32	1.70	22.71	0.09	0.00	99.66	10.7	27.4	61.9
Dp5-3	锰钙辉石	50.16	0.00	0.19	7.37	17.58	1.66	22.30	0.09	0.00	99.36	10.5	26.2	63.3
注:样品由中国地质科学院矿产资源研究所电子探针室分析;Di-透辉石;Hed-钙铁辉石;Jo-锰钙辉石。

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表 3 大排蚀变花岗闪长岩锆石SHRIMP U-Pb年龄数据(D82)

Table 3 SHRIMP U-Pb dating of zircons from alteration granodiorite in ores of the Dapai Fe-Pb-Zn

测点号	U/10^'6	Th/10^'6	Th/U	f₂₀₆^#/%	²⁰⁶Pb^*/²³⁸U(±l)		²⁰⁷Pb^*/²³⁵U(±l)		²⁰⁷Pb^/²⁰⁶Pb^(±l)		²⁰⁶Pb/²³⁸U 年龄 /Ma (±1)		²⁰⁷Pb/²⁰⁶Pb年龄 /Ma(±1)
1	1334	1512	1.17	1.06	0.0201	2.5	0.13	5.5	0.0485	4.9	128.0	4.0	121	115
2	178	158	0.92	5.54	0.0194	2.8	0.15	27.9	0.0549	27.7	123.7	4.5	408	619
3	670	896	1.38	0.75	0.0206	2.5	0.14	4.6	0.0482	3.8	131.3	4.3	110	90
4	957	1979	2.14	1.15	0.0206	2.5	0.13	5.8	0.0475	5.3	131.6	5.2	75	125
5	332	307	0.96	4.00	0.0203	2.7	0.10	20.2	0.0383	20.1	129.3	4.1	-467	530
6	764	798	1.08	1.11	0.0207	2.6	0.14	7.9	0.0501	7.4	132.3	4.1	200	173
7	669	1076	1.66	0.96	0.0203	2.5	0.14	6.5	0.0515	5.9	129.3	4.6	264	136
8	515	589	1.18	1.11	0.0185	2.6	0.13	7.8	0.0511	7.4	118.3	3.9	248	169
9	705	781	1.14	2.15	0.0203	2.5	0.11	8.9	0.0405	8.6	129.3	4.1	-319	220
10	642	981	1.58	1.30	0.0202	2.5	0.15	11.5	0.0522	11.2	128.8	4.5	295	257
11	654	619	0.98	1.10	0.0198	2.5	0.14	10.0	0.0522	9.7	126.3	3.9	294	221
12	550	707	1.33	1.00	0.0190	2.8	0.12	7.5	0.0459	6.9	121.2	4.4	-5	166
13	479	440	0.95	1.73	0.0197	2.6	0.13	10.3	0.0491	9.9	125.9	3.9	152	233
14	857	692	0.83	0.94	0.0201	2.6	0.13	7.0	0.0471	6.4	128.3	3.9	54	154

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表 4 福建大排铁铅锌矿花岗闪长斑岩中辉钼矿Re-Os同位素数据

Table 4 Re-Os isotopic analyses of molybdenite from ores of the Dapai Fe-Pb-Zn deposit

样号	样重/g	w_(Re)/10^-6		w_(普Os)/10^-6		w(¹⁸⁷Re)/10^'6		w(¹⁸⁷Os)/10^'9		模式年龄/Ma
样号	样重/g	测定值	不确定度	测定值	不确定度	测定值	不确定度	测定值	不确定度	测定值	不确定度
ZK-4	0.00603	99.54	0.82	0.0102	0.0342	62.56	0.51	137.6	1.2	131.8	1.9
ZK-2	0.00170	192.8	1.6	2.516	0.267	121.1	1.0	264.9	3.1	131.1	2.2
ZK-3	0.00213	830.7	6.5	3.119	0.262	522.1	4.1	1164	9	133.7	1.9
ZK-6	0.00508	442.7	4.7	1.066	0.179	278.3	3.0	610.5	5.2	131.5	2.1

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表 5 二长花岗斑岩等4种元素含量(10^-6)

Table 5 Four elements of monzonitic granite porphyry from the Dapai Fe-Pb-Zn deposit (10^-6)

类别	Cu	Pb	Zn	Mo
二长花斑岩	20~60	20~80	< 100	≤10~20
蚀变辉绿闪长岩(D82-1)	15.5	28.8	364.35	270
矽卡岩化岩体	200-340	150-200	250	10

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