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    青海省德令哈市某铅锌选矿厂土壤重金属垂向分布特征及污染风险评估

    Vertical distribution characteristics and pollution risk assessment of heavy metals in soil of a lead-zinc concentrator in Delingha, Qinghai Province

    • 摘要:
      研究目的 为研究铅锌选矿厂土壤重金属的垂向分布特征并科学合理的评估其重金属污染风险。
      研究方法 本文以青海省德令哈市某铅锌矿选矿厂为例,野外通过网格化布点,共采集0~20 cm的表层土壤样品132个,布设土壤垂向剖面43个,采集20~700 cm不同深度的深层土壤样品242件。分析测试了不同深度土壤中As、Cd、Cr6+、Cu、Pb、Hg、Ni、Zn含量,通过对比重金属在选矿厂土壤埋深0~7 m范围内含量的变化,分析重金属的垂向分布特征,并采用单因子指数法、内梅罗综合污染指数法和潜在生态风险评价指数法分别对选矿厂土壤中重金属污染程度和潜在生态风险进行评估。
      研究结果 (1)选矿厂超标重金属As主要分布在尾矿库,垂向富集范围主要集中在地表以下0~2 m;Pb主要分布在尾矿库、循环水池、选矿区,垂向富集范围主要集中在地表以下0~6 m。(2)选矿厂土壤重金属平均含量表现为Pb >Zn >Cu >As >Cr6+ >Ni >Cd >Hg。(3)就重金属污染程度而言,选矿厂土壤5种重金属处于无污染状态,As和Pb分别以占表层土壤33.33%、34.85%的样品处于重污染状态。(4)潜在污染风险评价指数结果显示选矿厂整体处于强潜在生态风险,Cd和Hg为极强风险,Pb为强风险,As为中风险,Cr、Ni、Zn、Cu为轻微风险。
      结论 (1)选矿厂超标重金属As垂向富集范围主要集中在地面下0~2 m内,Pb垂向富集范围主要集中在地面下0~6 m内。(2)选矿厂整体处重污染水平和重污染生态风险程度,超标元素As和Pb主要来源于铅锌选矿时尾矿淋溶、循环水下渗、生产粉尘沉降等生产活动。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective This study aims to investigate the vertical distribution characteristics of heavy metals in the soils of a lead-zinc concentrator and to assess the associated heavy metal pollution risk in a scientific and reasonable manner.
      Methods Taking a lead-zinc concentrator in Delingha City, Qinghai Province, as a case study, a grid-based sampling layout was implemented in the field. A total of 132 surface soil samples were collected from the 0-20 cm layer, 43 vertical soil profiles were established, and 242 deep soil samples were collected at varying depths of 20-700 cm. The concentrations of As, Cd, Cr6+, Cu, Pb, Hg, Ni and Zn in soils at different depths were determined. By comparing the variations in heavy metal concentrations within the 0-7 m buried-depth interval of the concentrator soils, the vertical distribution characteristics of these heavy metals were analyzed. The single-factor index method, the Nemerow comprehensive pollution index method, and the potential ecological risk assessment index method were then applied to evaluate the degree of heavy metal pollution and the potential ecological risk in the concentrator soils, respectively.
      Results (1) As, one of the heavy metals exceeding the standard limits in the concentrator, is mainly distributed in the tailings pond, with its vertical enrichment range concentrated within 0-2 m below the ground surface; Pb is mainly distributed in the tailings pond, the circulating water pond, and the beneficiation area, with its vertical enrichment range concentrated within 0-6 m below the ground surface. (2) The average concentrations of heavy metals in the concentrator soils decrease in the order of Pb > Zn > Cu > As > Cr6+> Ni > Cd > Hg. (3) In terms of pollution degree, five heavy metals in the concentrator soils remain at a clean (non-pollution) level, whereas As and Pb reach the heavy pollution level in 33.33% and 34.85% of the surface soil samples, respectively. (4) The potential ecological risk index results show that the concentrator as a whole is subject to a strong potential ecological risk: Cd and Hg pose extremely strong risks, Pb a strong risk, As a moderate risk, and Cr, Ni, Zn, and Cu slight risks.
      Conclusions (1) The vertical enrichment of As, a heavy metal exceeding the standard limit in the concentrator, is mainly confined to the interval of 0-2 m below the ground surface, and that of Pb is mainly confined to 0-6 m below the ground surface. (2) The concentrator as a whole is at a heavy pollution level with a correspondingly high degree of ecological risk. The standard-exceeding elements As and Pb originate mainly from production activities during lead–zinc beneficiation, such as tailings leaching, downward infiltration of circulating water, and deposition of production dust.

       

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