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    湖南省龙山县土壤重金属特征与健康风险评价

    Characteristics and health risk evaluation of soil heavy metals in Longshan County, Hunan Province

    • 摘要:
      研究目的 在龙山县采集土壤样品775件,分析土壤重金属As、Cd、Cr、Cu、Hg、Ni、Pb、Zn的含量特征,评价土壤重金属造成的健康风险。
      研究方法 利用地累积指数进行了土壤重金属污染评价,基于相关性分析和主成分分析讨论了土壤重金属的来源,采用健康风险模型评估了土壤重金属对人体产生的健康风险。
      研究结果 龙山县土壤中Cd含量的平均值明显高于湖南省土壤背景值,表明龙山县土壤中Cd存在一定程度的富集。As和Cd的变异系数均大于0.5,Hg的变异系数大于1,可能受到人类活动的影响。龙山县土壤中存在不同程度的As、Cd、Cr、Cu、Hg、Ni、Pb、Zn污染,其中,Cd污染范围较广,局部地区Hg污染程度严重。龙山县土壤重金属来源可分为三类:Cr、Cu、Ni主要来源于成土母质;As、Cd、Pb、Zn主要来源于铅锌矿开采选冶,同时,Cd的来源与地质背景有一定的关系;Hg主要来源于化石燃料燃烧。龙山县土壤重金属对儿童造成的健康风险高于成人,需注意龙山县里耶镇、苗儿滩镇和洛塔乡土壤重金属产生的健康风险。此外,As、Cr是造成非致癌风险的主要重金属元素,Cr、Ni是造成致癌风险的主要重金属元素,经口摄入是产生健康风险主要暴露途径。
      结论 龙山县土壤中重金属存在不同程度的污染,As、Cd、Ni是健康风险的主要贡献因子。

       

      Abstract:
      This paper is the result of geological survey engineering.
      Objective A total of 775 soil samples were collected in Longshan County to analyze the content characteristics of heavy metals in soil, including As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn, and to evaluate the health risks associated with these contaminants.
      Methods The geo−accumulation index was applied to assess soil heavy metal pollution levels. Correlation analysis and principal component analysis were used to identify the sources of soil heavy metals. A health risk model was employed to evaluate the potential risks posed by these metals to human health.
      Results The analysis revealed that the average Cd concentration in Longshan County soils significantly exceeds the background value for Hunan Province, indicating a certain degree of Cd enrichment. The variation coefficients for As and Cd exceeded 0.5, while Hg's coefficient surpassed 1, suggesting a potential influence from human activities. Various degrees of contamination by As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn were identified, with widespread Cd pollution and severe Hg contamination in certain areas. The sources of these heavy metals were categorized into three groups: (1) Cr, Cu, and Ni primarily originate from soil parent materials; (2) As, Cd, Pb, and Zn are largely linked to lead−zinc mining and smelting, with Cd also showing some association with geological background; (3) Hg primarily stems from fossil fuel combustion. The health risk assessment indicated that children face higher risks from soil heavy metals compared to adults. Attention should be focused on the health risks in Liye Town, Miaoertan Town, and Luota Town. As and Cr were identified as the primary contributors to non−carcinogenic risks, while Cr and Ni were the main contributors to carcinogenic risks. Oral ingestion was found to be the dominant exposure pathway for health risks.
      Conclusions Heavy metal pollution in Longshan County soils exists at varying levels. As, Cd, and Ni are the primary contributors to health risks.

       

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