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    南秦岭武当地区蒿坪脉石英型高纯石英矿成因机理及其找矿潜力评价

    Ore genesis and prospecting potential of the Haoping hydrothermal vein-type high-purity quartz deposit in the Wudang Uplift, South Qinling

    • 摘要:
      研究目的 脉石英是生产制备高纯石英的重要原料之一。由于经历了多期次的构造–岩浆活动,南秦岭武当地区广泛发育着脉石英矿床。为研究区域成矿规律和矿石原料特征,本文以蒿坪脉石英为研究对象,分析了该矿床的矿床地质特征,揭示了其成因机理,并探讨了其高纯石英可制备性和找矿潜力。
      研究方法 本文在野外地质调查成果的基础上,基于矿石化学成分分析、流体包裹体显微测温和同位素分析等方法研究了蒿坪脉石英的成因机制、矿石品质和找矿潜力。
      研究结果 蒿坪石英Rb−Sr年代学研究获得其成矿年龄为(302.7±6.7) Ma。石英的Al、Ti、Li、B、Fe、Na、K和Ca等杂质元素总量介于53.61×10−6~71.46×10−6。此外,蒿坪脉石英矿成矿流体的温度和盐度分别变化于225~475 ℃和2.57%~9.73% NaCl equiv.,具有中—高温和中—高盐度的属性;成矿流体的\delta ^18\rmO_\rmH_\rm2\rmO变化于+7.5‰~+8.6‰,\delta \rmD_\rmH_\rm2\rmO 范围为−96.5‰~−72.9‰,初始的87Sr/86Sr值为0.72020~0.72074。
      结论 蒿坪脉石英矿是由深部的酸性岩浆岩演化出的富SiO2的流体沿断裂充填形成,并具备很好的4N5级高纯石英找矿潜力。

       

      Abstract:
      This paper is the result of mineral exploration engineering.
      Objective Vein−type quartz deposit is one of the critical raw materials for the production of high−purity quartz. Due to the occurrence of multiple episodes of tectonic−magmatic activities, the Wudang uplift of South Qinling is widely exposed vein−type quartz deposits. In order to investigate the regional metallogenic mechanism and the characteristics of ore materials, we analyzed the geological features, genetic mechanism and prospecting potential of the Haoping vein−type quartz deposit.
      Methods Based on the results of field geological surveys, we used chemical composition analysis of ores, microthermometry of fluid inclusions and isotopic analysis of quartz to reveal the genetic mechanism, ore quality and prospecting potential of the Haoping vein−type quartz deposit in this manuscript.
      Results Rb−Sr dating on the quartz grains yields an isochron age of (302.7±6.7) Ma. Bulk solution analysis demonstrates that the quartz grains has low total impurity concentrations, with the values range from 53.61×10−6 to 71.46×10−6. At Haoping deposit, the fluid inclusions studies indicate that the temperature and salinity of the ore−forming fluids range from 225 to 475 ℃ and from 2.57% to 9.73% NaCl equiv., respectively, exhibiting clear features of medium−high temperature and medium−high salinity. In addition, the δ18OH2O and δDH2O values of fluids in equilibrium with quartz, rang from +7.5‰ to +8.6‰ and from −96.5‰ to −72.9‰, respectively, with the (87Sr/86Sr)i values are 0.72020 to 0.72074.
      Conclusions Integrating the data obtained from studies on geology and fluid sources, we propose that the Haoping deposit was formed by the precipitation of SiO2−rich fluids which evolved from deep acidic magmatic rocks and migrated along faults. In addition, the Haoping deposit has a good potential for 4N5−grade high−purity quartz prospecting.

       

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