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    滇中某典型砂岩型铜矿区周边土壤重金属来源解析及健康风险评价

    Health risk assessment and source apportionment of heavy metals in the surrounding soil of a sandstone copper mine area in Central Yunnan

    • 摘要:
      研究目的 滇中地区是重要的铜矿和粮食产区,剖析砂岩型铜矿区周边土壤重金属空间分布特征,明确污染源及其健康风险,对金属矿区生态环境保护治理和确保农业安全具有重要现实意义。
      研究方法 基于网格布点法在滇中某典型砂岩型铜矿区周边采集土壤样品780件,分析了土壤pH、Corg、As、Cd、Cr、Cu、Hg、Ni、Pb和Zn等含量,通过正定矩阵因子分析(PMF)和地理探测器模型解析了重金属潜在来源,运用健康风险模型计算不同污染源产生的非致癌风险和致癌风险。
      研究结果 8种重金属含量的最大值是背景值的2.49~36.88倍,其中部分样品Cd和As含量高于国家标准规定的风险筛选值和管控值,重金属高值区主要集中在铜矿采冶区附近。来源解析显示,重金属积累受母岩风化自然源(27.9%)、废渣源(17.8%)、含铅母岩自然源(15.4%)、含铜母岩自然源(15.2%)、落后工艺采冶铜矿源(12.5%)以及大气沉降源(11.2%)这6个来源的影响。健康风险评估结果显示,落后工艺采冶铜矿污染源对儿童和成人的非致癌风险指数(HI)贡献最大(分别为35.6%和5.8%)。全部样点对成人的HI均在限值范围内,但有12.31%的样点对儿童的HI高于限值,有1.14%和5.51%的样点分别对成人和儿童的致癌风险指数(CRI)高于限值。在所有暴露途径中,经口摄入(86.84%~93.28%)对健康风险的贡献最大。
      结论 儿童需要更多关注和引导,以降低重金属经口摄入风险,制定砂岩型铜矿区周边土壤保护策略时应优先考虑严格控制采冶铜矿中使用古法炼铜等落后工艺。本研究为制定针对性的污染源防控措施提供了支撑。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective Central Yunnan area is an important copper mine and grain production area. Analyzing the spatial distribution of heavy metals in soil around sandstone copper mine areas, identifying pollution sources and health risks is of great practical significance for ecological environment protection and governance in metal mine areas and ensuring agricultural safety.
      Methods Based on the grid sampling method, 780 soil samples were collected around a typical sandstone copper mine. The contents of Corg, As, Cd, Cr, Cu, Hg, Ni, Pb, Zn and pH in soil were analyzed. The potential sources of heavy metals were analyzed through positive definite matrix factor analysis (PMF) model and Geodetector. The non−carcinogenic and carcinogenic risks generated by different pollution sources were assessed using a health risk model.
      Results The maximum concentrations of the eight heavy metals were 2.49−36.88 times the background value. Some Cd and As concentrations exceeded the risk screening and control values stipulated by China’s national standards. The areas with high metal levels were mainly near copper mining and smelting areas. Source analysis revealed that the accumulation of heavy metals was affected by 6 sources: natural sources from parent rock weathering (27.9%), waste residues source (17.8%), natural sources of lead−bearing parent rock (15.4%), natural sources of copper−bearing parent rock (15.2%), copper mining and smelting practices with outdated technology source (12.5%), and atmospheric deposition source (11.2%). Health risk assessment results demonstrated that copper mining and smelting practices with outdated technology source contributed the most to the hazard index (HI) in both children and adults (35.6% and 5.8%, respectively). The potential non−carcinogenic risk to adults from soil heavy metals was regarded as acceptable. However, among the samples, 12.31% presented a higher potential non−carcinogenic risk to children. Additionally, 1.14% and 5.51% of the samples that exceeded the established limits posed a higher carcinogenic risk to adults and children respectively. Among all exposure pathways, the soil ingestion pathway (86.84% to 93.28%) contributed the most to health risks.
      Conclusions To reduce children's heavy metal ingestion risk via the oral route, more attention and guidance are needed. When formulating soil protection strategies near sandstone copper mining areas, regulating backward technologies (such as ancient copper smelting) in mining and smelting should be a top priority. The research findings support formulating targeted pollution source prevention and control measures.

       

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