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    渤海海峡西南部表层海水重金属分布、来源与生态风险

    Distribution, source and ecological risk of heavy metals in surface seawater of the Southwestern Bohai Strait

    • 摘要:
      研究目的 海水重金属污染对渤海海峡西南部海洋生态环境产生长期不利影响,然而其重金属的污染评价和潜在来源研究相对薄弱。
      研究方法 2021年9—10月采集该区域43个站位表层海水样品,测定6种重金属元素(Cu、Pb、Zn、Cd、Cr、As)的含量,运用地累积指数(Igeo)法、权重修正内梅罗指数法和风险熵评价法(FQ)进行污染和风险评价,结合相关性分析和空间分布特征,运用主成分分析(PCA)、正定矩阵因子分解(PMF)模型进行源解析。
      研究结果 Cr、Cu、Cd、Pb、As和Zn元素平均含量分别为0.63 μg/L、3.09 μg/L、0.12 μg/L、0.57 μg/L、1.30 μg/L和13.04 μg/L,Zn元素含量超过了渤海海域平均水平,重金属元素空间分布上受养殖区和航道的影响较大。单因子污染指数大小为:Zn>Cu>Pb>Cd>As>Cr,其中Cu、Zn和Pb元素存在部分站位超标,Zn元素超标最为严重。从修正内梅罗综合污染程度来看,海水整体质量较好,存在个别轻度—中度污染站位,主要受Pb、Zn元素的控制,在大黑山岛以西、以北呈多点状分布。潜在生态风险评价结果表明,Cu、Zn元素大部分站位都处在高潜在生态风险范围内,存在明显潜在生态风险。PMF模型解析结果表明研究区重金属污染来源主要包括工业污染、黄河输入及自然风化、大气沉降以及渔业养殖和海上交通运输,贡献率分别为20.94%、61.61%、4.25%和13.20%。
      结论 工业污染和黄河物质输入给渤海海峡西南部海洋生态环境带来较大潜在风险,下一步要加强关注不同介质中Cu、Zn变化趋势及对研究区内海洋生物的影响。

       

      Abstract:
      This paper is the result of marine and environmental geological survey engineering.
      Objective Heavy metal pollution in seawater had long−term adverse effects on the marine ecological environment in the southwest of the Bohai Strait, but the researches focused on evaluation and potential sources of heavy metal pollution were relatively weak.
      Methods 43 samples were collected in September and October 2021, and the contents of 6 seawater heavy metals (Cu, Pb, Zn, Cd, Cr, As) were determined. The pollution and risk assessment was carried out by Igeo, Nemero pollution index with weight modification and FQ. The analysis source of heavy metals was explored by correlation analysis and spatial distribution characteristics, and was carried out by PCA and positive matrix factorization (PMF) model.
      Results The average mass concentrations of Cr, Cu, Cd, Pb, As and Zn were 0.63 μg/L, 3.09 μg/L, 0.12 μg/L, 0.57 μg/L, 1.30 μg/L and 13.04 μg/L, respectively. The content of Zn element exceeded the average level in the Bohai Sea, and the spatial distribution of heavy metal elements is greatly influenced by aquaculture areas and waterways.The size of the single factor pollution index of seawater heavy metals was arranged in the order of Zn>Cu>Pb>Cd>As>Cr. Some sites of Cu, Zn and Pb exceed the standard, and Zn was the most severely. The results of Nemero pollution index with weight modification indicated that the overall quality of seawater were good. The minor stations of mild to moderate pollution which mainly affected by Pb and Zn were distributed in a multi-point pattern west and north of Daheishan island. The results of FQ indicated that Cu and Zn posed high potential ecological risks. The analysis results of the PMF indicated that the sources of heavy metal pollution in the study area mainly included industrial pollution, input of the Yellow River and natural weathering, atmospheric deposition, aquaculture and maritime transportation, with contribution rates of 20.94%, 61.61%, 4.25% and 13.20%, respectively.
      Conclusions Industrial pollution and the Yellow River's material input pose significant potential risks to the marine ecological environment in the southwest of the Bohai Strait. The next step is to pay more attention to the trends of Cu and Zn changes in different media and their impact on marine organisms in the study area.

       

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