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    黄河入海口三角洲地区土壤重金属污染特征、来源分析及风险评价

    Soil heavy metal pollution characteristics, sources and risk assessment in the Yellow River Estuary Delta region

    • 摘要:
      研究目的 黄河三角洲是中国最大最年轻的河口湿地,拥有世界上最年轻的湿地生态系统,生态环境脆弱,掌握黄河三角洲重金属污染特征及其来源,对该地区生态保护和重金属污染防控具有重要意义。
      研究方法 本研究于2022年5—6月在三角洲地区采集400件0~20 cm表层土壤样品,测定了Zn、Cr、Ni、Cu、Pb、As、Cd和Hg 8种重金属含量,运用相关性分析和主成分分析的方法探索土壤重金属的来源,运用单因子污染指数法、内梅罗综合污染指数法和地累积指数法确定其污染程度,采用人体健康风险评价的方法评估其风险。
      研究结果 (1)研究区土壤pH平均值为8.46,Zn、Cr、Ni、Cu、Pb、As、Cd和Hg在土壤中的平均含量依次为72.38 mg/kg、71.33 mg/kg、32.44 mg/kg、26.12 mg/kg、17.94 mg/kg、12.20 mg/kg、0.14 mg/kg和0.03 mg/kg。(2)单项污染评价、地累积指数法结果显示研究区土壤污染总体处于轻度污染以内。(3)健康风险评估表明,经口摄入是引起非致癌、致癌健康风险的主要途径,儿童非致癌风险大于成人,所有样品致癌健康风险指数小于10−4
      结论 黄河入海口三角洲地区土壤重金属污染程度较低,整体生态风险较小。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective The Yellow River Delta is the largest and youngest estuarine wetland in China, hosting one of the world's most fragile and youngest wetland ecosystems. Understanding the characteristics and sources of heavy metal pollution in this region is crucial for ecological protection and pollution control.
      Methods In May–June 2022, 400 surface soil samples of 0−20 cm soil depth were collected from this region, and concentrations of eight heavy metals, including Zn, Cr, Ni, Cu, Pb, As, Cd and Hg, were measured. Pollutions sources were idientified by the correlation analysis and principal component analysis. Pollution levels were evaluated by using methods, including the single−factor pollution index (Pi), Nemerow composite pollution index (PN), and geo-accumulation index (Igeo). Human health risk assessment methods were applied to evaluate potential risks.
      Results (1) In the research sites soil pH was 8.46. The concentrations of Zn, Cr, Ni, Cu, Pb, As, Cd and Hg were 72.38 mg/kg, 71.33 mg/kg, 32.44 mg/kg, 26.12 mg/kg, 17.94 mg/kg, 12.2 mg/kg, 0.14 mg/kg, and 0.03 mg/kg, respectively. (2) Both the single-factor pollution index and geo-accumulation index indicated that the overall soil pollution level was within the mild range. (3) Health risk assessment revealed that oral ingestion was the primary pathway for non-carcinogenic and carcinogenic risks. Children faced higher non-carcinogenic risks than adults, while all samples exhibited carcinogenic risk indices below 10−4.
      Conclusions The soil heavy metal pollution in the Yellow River Delta is relatively low, posing minimal ecological risks.

       

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