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    四川盆地东南缘洞子沟铅锌矿床成因机制——来自流体包裹体、C−H−O和Rb−Sr同位素的证据

    Genesis of the Dongzigou Pb−Zn deposit in the southeast margin of Sichuan Basin: Evidence from fluid inclusions, Rb−Sr and C−H−O isotopes

    • 摘要:
      研究目的 洞子沟铅锌矿床位于四川盆地东南缘桑木场铅锌成矿带,是该成矿带内具有代表性的富有机质铅锌矿床。本文通过查明该矿床成矿流体性质及演化过程,结合闪锌矿Rb−Sr定年结果,建立铅锌成矿模式,将进一步完善盆地周缘富有机质铅锌资源的成矿认识。
      研究方法 本文基于详细的基础地质特征研究和矿物学研究,开展流体包裹体岩相学观察、包裹体显微测温以及拉曼光谱测试,结合C−H−O同位素组成特征和闪锌矿Rb−Sr同位素等时线年龄,理清铅锌成矿过程,建立成矿模式。
      研究结果 流体包裹体岩相学显示主要成矿阶段流体包裹体以富液相包裹体(LV)为主,结合激光拉曼分析,指示成矿流体属NaCl−H2O体系。显微测温结果显示成矿流体总体上属于中低温、中低盐度、中低密度流体。C−H−O同位素组成特征表明成矿流体与海相碳酸盐岩密切相关,早阶段成矿流体以地层建造水为主,中晚阶段伴有大气降水的混入,且在成矿作用过程中发生了碳酸盐岩溶解作用。闪锌矿87Rb/86Sr−87Sr/86Sr同位素等时线图解显示洞子沟矿床其等时线年龄为(135.2±6.1)Ma,MSWD=1.10。
      结论 该矿床铅锌沉淀机制以成矿流体与大气降水的不等温混合作用为主,燕山期构造隆升运动不仅为矿床提供良好的导矿、容矿空间,还驱动成矿流体运移并与大气降水混合,进而降低流体对铅锌的溶解度,促使铅锌矿物沉淀富集。

       

      Abstract:
      This paper is the result of mineral exploration engineering.
      Objective The Dongzigou lead−zinc deposit is located in the Sangmuchang lead−zinc metallogenic belt on the southeastern margin of the Sichuan Basin, and it is a representative lead−zinc deposit rich in organic matter within this metallogenic belt. In this paper, by investigating the properties and evolution process of the metallogenic fluid of this deposit and combining with the Rb−Sr dating results of sphalerite, a lead−zinc metallogenic model will be established, which will further improve the metallogenesis of lead−zinc resources rich in organic matter around the basin.
      Methods Based on detailed studies on basic geological characteristics and mineralogy, this paper conducts petrographic observations of fluid inclusions, microthermometric measurements of fluid inclusions and Raman spectroscopy tests. Combined with the characteristics of C−H−O isotope compositions and the isochron ages of Rb−Sr isotopes of sphalerite, it clarifies the lead−zinc metallogenic process and establishes the metallogenic model.
      Results Petrography of fluid inclusions shows that fluid inclusions in the main metallogenic stage are mainly liquid−rich inclusions (LV). Combined with laser Raman analysis, it indicates that the metallogenic fluid belongs to the NaCl−H2O system. The results of microthermometry demonstrate that the metallogenic fluid is generally of medium−low temperature, medium−low salinity and medium−low density. The characteristics of C−H−O isotope compositions suggest that the metallogenic fluid is closely related to marine carbonate rocks. In the early stage, the metallogenic fluid is mainly formation water, and in the middle and late stages, meteoric water is mixed in. Moreover, carbonate rock dissolution occurred during the metallogenic process. The isochron diagram of 87Rb/86Sr−87Sr/86Sr isotopes of sphalerite shows that the isochron age of the Dongzigou deposit is (135.2±6.1) Ma with MSWD = 1.10.
      Conclusions The lead−zinc precipitation mechanism of this deposit is dominated by the non−isothermal mixing of ore−forming fluids and meteoric water. The Yanshanian tectonic uplift not only provided favorable ore−conducting and ore−hosting spaces for the deposit, but also drove the migration of ore−forming fluids and their mixing with meteoric water. This process further reduced the solubility of lead and zinc in the fluids, thereby facilitating the precipitation and enrichment of lead−zinc minerals.

       

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