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    典型锂矿区土壤重金属特征、来源分析、对生态环境的影响及绿色矿业开发建议—以川西阿拉伯和观音桥为例

    Characteristics, source analysis, and ecological impacts of soil heavy metals in typical lithium mining areas with recommendations for green mining development: A case study of the Alabo and Guanyinqiao lithium mining areas in Western Sichuan

    • 摘要:
      研究目的 充分了解已开采的稀有金属矿区土壤重金属特征,解析重金属来源及对生态环境的影响,提出川西锂资源绿色开发建议。
      研究方法 本研究以川西大型锂资源基地内资源枯竭的阿拉伯锂矿区和观音桥锂矿区为对象,分别采集了48个和25个表层土壤样本,测定了Cu、Pb、Cr、Ni、Cd、As、Hg、Zn八种重金属的含量及pH值。采用单因子污染指数法、内梅罗综合污染指数法、地累积指数法、潜在生态风险评价法相结合,综合评估了重金属污染状况和潜在生态风险,并利用相关性分析和主成分分析,探讨了重金属来源。
      研究结果 阿拉伯和观音桥锂矿区土壤重金属含量均低于背景值或相差不大。重金属在空间分布上呈斑块状富集,集中在人类活动密集区域。单因子污染指数和综合污染指数显示两矿区土壤未受污染;地累积指数表明除Cd外其余元素无污染积累;潜在生态风险评价显示,Cd和Hg存在轻微至中等潜在危害风险,但综合生态风险指数表明矿区总体风险较低。重金属来源分析表明,Cu、Cr、Ni、Pb、Zn主要来源于自然源(如岩石风化),Cd和Hg主要由人为活动(特别是选矿)造成,而As则受自然与人为因素共同影响。
      结论 川西锂矿资源开发不会对生态环境造成广泛影响,仅在人类活动密集区(如选矿池、尾矿库)出现Cd、Hg等重金属富集现象,影响有限。强化源控制可避免矿业开发对生态环境造成的影响。综合阿拉伯和观音桥锂矿区土壤重金属特征、来源及对生态环境的影响,提出了未来绿色矿业开发建议。

       

      Abstract:
      This paper is the result of ecological geological survey engineering.
      Objective This paper aims to thoroughly understand the characteristics of heavy metals in soils of mined rare metal mining areas, analyze the sources of heavy metals and their impact on the ecological environment, and propose recommendations for the green development of lithium resources in western Sichuan.
      Methods This study focused on the depleted Alabo and Guanyinqiao lithium mining areas within the large lithium resource base in western Sichuan. A total of 48 and 25 surface soil samples were collected from the two sites, respectively. The contents of eight heavy metals (Cu, Pb, Cr, Ni, Cd, As, Hg, Zn) and pH values were measured. The pollution status and potential ecological risks of heavy metals were comprehensively evaluated using the Single Factor Pollution Index, Nemerow Comprehensive Pollution Index, Geo-accumulation Index, and Potential Ecological Risk Assessment. Correlation analysis and principal component analysis were employed to explore the sources of heavy metals.
      Results The heavy metal contents in the soils of both lithium mining areas were either lower than or similar to the background values. Spatially, heavy metals showed patchy enrichment, concentrated in areas with intensive human activities. Both the Single Factor and Comprehensive Pollution Indices indicated no pollution in the soils of the two mining areas. The Geo-accumulation Index showed no accumulation of pollution for all elements except Cd. The Potential Ecological Risk Assessment revealed slight to moderate potential risks from Cd and Hg, but the comprehensive ecological risk index indicated an overall low risk in the mining areas. Source analysis indicated that Cu, Cr, Ni, Pb, and Zn were primarily derived from natural sources (e.g., rock weathering), Cd and Hg were mainly attributed to human activities (particularly mineral processing), while As was influenced by both natural and anthropogenic factors.
      Conclusions Lithium mining in western Sichuan poses limited ecological risks, with Cd and Hg enrichment observed only in human activity-intensive areas (e.g., processing ponds, tailings dams). Strengthened source control can mitigate mining-related ecological impacts. Based on heavy metal characteristics, source attribution, and ecological evaluations, practical recommendations for green mining development are proposed.

       

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