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    黑龙江宁安市土壤重金属元素地球化学特征分析及污染评价

    Geochemical characterization and contamination assessment of heavy metals in soils of Ning'an city, Heilongjiang Province, China

    • 摘要:
      研究目的 黑龙江省宁安市是全国83个黑土地重点保护县市之一,查明宁安市土壤重金属元素分布特征及环境质量情况,对打造“百公里东北亚高端食品农产品和文化生态产业走廊”有重要意义。
      研究方法 系统采集70个表、深层土壤样品,测定Zn、Ni、Cd、Cu、Cr、Pb、As、Hg 八项重金属元素含量,采用数据统计和地理空间分析方法,揭示其分布及富集特征,采取相关性和主成分分析方法追溯重金属来源,运用地质累积指数和内梅罗综合指数法开展土壤污染评价。
      研究结果 (1)宁安地区Hg、Cd、Ni、As 四类重金属元素变异系数均>36%,受人类活动影响较大。(2)Ni、Cu、Cr 三类元素来源主要为深部母岩或风化物母质;Pb和As元素主要受农业活动影响;Zn、Cd和Hg元素主要受人类活动和地质背景双重影响。(3)宁安地区不同重金属元素深层土壤富集程度差异较大,大部分以无富集、轻度富集为主。(4)地质累积指数法评价结果显示,除Cr元素轻微污染点位占比达63.77%外,其他重金属元素轻微污染点位未超过25%。(5)内梅罗综合污染指数法结果表明,宁安地区重金属元素单项污染指数大小排序为Cr>Ni>As>Cd>Cu>Zn>Pb>Hg。除Hg元素尚清洁和Cr元素中度污染外,其余土壤中重金属单项污染指数均以轻污染为主。
      结论 宁安地区土壤存在重金属轻微污染问题,建议在采矿作业,农业生产等人类活动中注意加强防范措施。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective Ning'an City, Heilongjiang Province, is one of the 83 key protected counties and cities for black soil nationwide. Investigating and characterizing the distribution characteristics of heavy metal elements in soil and the environmental quality status in Ning'an City hold significant importance for developing the "100-kilometer northeast asian high-end food, agricultural products, and cultural ecological industry corridor".
      Methods 70 surface and deep soil samples were collected systematically to determine the contents of eight heavy metals, including Zn, Ni, Cd, Cu, Cr, Pb, As and Hg. Data statistics and geospatial analysis were used to reveal their distribution and enrichment characteristics. Correlation and principal component analysis were used to trace the sources of heavy metals. The cumulative geological index and Nemerow comprehensive index were used to evaluate soil pollution.
      Results (1) The coefficient of variation of Hg, Cd, Ni and As heavy metals in Ning'an area was more than 36%, which was greatly affected by human activities. (2) Ni, Cu and Cr are mainly derived from deep parent rock or weathered material; Pb and As are mainly affected by agricultural activities; Zn, Cd and Hg are mainly affected by human activities and geological background. (3) The enrichment degree of different heavy metal elements in deep soil in Ning'an area is quite different, and most of them are non enriched and slightly enriched. (4) The evaluation results of geological cumulative index method showed that except for the slight pollution of Cr, which accounted for 63.77%, the slight pollution of other heavy metals did not exceed 25%. (5) The results of the nemerow comprehensive pollution index method indicate that the ranking of individual pollution indices for heavy metal elements in Ning'an region is Cr > Ni > As > Cd > Cu > Zn > Pb > Hg. Except for Hg (which remains clean) and Cr (which is moderately polluted), the individual pollution indices of heavy metals in the remaining soils are primarily lightly polluted.
      Conclusions There is a slight pollution problem of heavy metals in the soil of Ning'an area. It is suggested to strengthen the preventive measures in mining operations, agricultural production and other human activities.

       

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