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    广西某锡矿区周边土壤重金属污染及风险评价

    Heavy metal pollution and risk assessment of soils around a tin mining area in Guangxi

    • 摘要:
      研究目的 本文采集某锡矿区周边表层土壤191件、8个柱状剖面32件样品,测定Cu、Pb、Zn、Cr、Ni、Cd、As、Hg 元素含量,系统评价土壤重金属污染状况与风险。
      研究方法 采用单项污染指数法、内梅罗综合污染指数法和健康风险评估模型,对该地区污染程度和人体健康风险进行评价。
      研究结果 (1)研究区土壤重金属平均含量表现为As>Zn>Cr>Cu>Pb>Ni>Cd>Hg,As、Cd为主要污染元素,前者受到母岩风化、矿冶业和农业活动综合影响,后者主要受到农业活动的影响;此外,水文条件对其重金属垂向分布具有控制作用;(2)重金属污染评价显示As为区内污染最严重的元素,其次为Cd,余下元素均以未污染和轻度污染为主;区内重金属整体以安全区–轻度污染为主;(3)健康风险评估显示,土壤中As为主要非致癌和致癌因子;经口摄入为最主要的暴露途径,儿童健康更易受到重金属污染的威胁。
      结论 目标锡矿区污染和健康风险均很低,整体安全可控;但农业活动引起的重金属污染需要引起重视。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective 191 surface soil samples and 32 samples from 8 columnar profiles in the vicinity of a tin mining area were collected to determine the contents of Cu, Pb, Zn, Cr, Ni, Cd, As, and Hg elements; and the heavy metal pollution status and risks were systematically evaluated.
      Methods The study adopted the Single Pollution Index method, Nemerow Comprehensive Pollution Index method, and Health Risk Assessment model to evaluate the pollution levels and human health risks in the area.
      Results (1) The average contents of heavy metals in soils of the study area are in the order of As>Zn>Cr>Cu>Pb>Ni>Cd>Hg. As and Cd are the primary pollution elements. The former is comprehensively influenced by parent rock weathering, mining and smelting industry, and agricultural activities, while the latter is mainly affected by agricultural activities. Additionally, hydrological conditions control the vertical distribution of heavy metals. (2) The evaluation of heavy metal pollution reveals that As is the most seriously polluted element in the area, followed by Cd, and the remaining elements are predominantly unpolluted or slightly polluted. Overall, the heavy metals in the study area is mainly in the safe to slightly polluted range. (3) The health risk assessment shows the As in the soil is the primary non-carcinogenic and carcinogenic factor; oral ingestion is the main exposure pathway, and children’s health is more vulnerable to heavy metal pollution.
      Conclusions The pollution and health risks in the target tin mining area are at a low level, and the overall situation is safe and controllable; however, the heavy metal pollution induced by agricultural activities requires attention.

       

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