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    安康盆地地下水重金属来源解析及健康风险评价

    Source apportionment and health risk assessment of heavy metals in groundwater in the Ankang basin

    • 摘要:
      研究目的 安康盆地是南水北调中线工程重要水源涵养区,研究其地下水质量对区域生态安全和饮水安全至关重要。该盆地夹持于秦岭与大巴山之间,浅层地下水以松散岩类孔隙水和基岩裂隙水为主,易受地表活动扰动。
      研究方法 通过采集37组浅层地下水样品,结合描述性统计、相关性分析、正定矩阵因子分解(PMF)模型及健康风险评价(HRA)模型,系统分析了安康盆地地下水重金属的含量特征、污染来源及健康风险。
      研究结果 研究区地下水重金属浓度均值按大小排序为Fe>Mn>Cu>Ni>Pb>As>Co>Cr(Ⅵ)>Cd>Hg,其中Fe、Mn、Pb在局部点位浓度超过《地下水质量标准》Ⅲ类限值;PMF源解析揭示重金属主要来源于工矿活动(56%)、农业和生活污染(29.65%)和矿物岩石风化(14.35%)。健康风险评价显示,As和Ni是引起安康盆地致癌风险的首要因子,非致癌风险整体较低,但Mn的潜在风险需要关注;饮水途径为主要暴露方式,儿童健康风险显著高于成人。
      结论 安康盆地西北部和东南部为地下水健康风险高值区,需优先管控。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective As an important water conservation area of the Middle Route of the South-to-North Water Diversion Project, the study of groundwater quality in Ankang Basin is very important for regional ecological security and drinking water safety. This basin is situated between the Qinling Mountains and the Daba Mountains. The shallow groundwater consists primarily of pore water in unconsolidated rocks and bedrock fracture water, making it susceptible to disturbance by surface activities.
      Methods Through collecting 37 shallow groundwater samples and employing integrated approaches including descriptive statistics, correlation analysis, Positive Matrix Factorization (PMF) modeling, and USEPA health risk assessment models, this study systematically examined the concentration characteristics, pollution sources, and health risks of heavy metals in the basin's groundwater.
      Results The mean concentrations of heavy metals followed the order: Fe>Mn>Cu>Ni>Pb>As>Co>Cr(Ⅵ)>Cd>Hg. Notably, Fe, Mn and Pb concentrations at specific locations exceeded the Class III limits of China's Groundwater Quality Standards. PMF source apportionment identified three primary contributors: industrial and mining activities (56%), combined agricultural and domestic pollution (29.65%), and mineral weathering (14.35%). Health risk assessment revealed that As and Ni were the predominant carcinogenic risk factors, while non-carcinogenic risks remained relatively low overall, though the potential risk of Mn warrants attention. Drinking water intake emerged as the primary exposure pathway, with children demonstrating significantly higher health risks than adults.
      Conclusions The northwestern and southeastern basin regions are priority areas for targeted management due to elevated risk levels.

       

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