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    长江三角洲某地区浅层地下水单环芳烃污染特征及其原因分析

    Characteristics and cause of monocyclic aromatic hydrocarbon contamination in shallow groundwater in an area of the Yangtze River delta

    • 摘要: 提要:本文针对长江三角洲某地区3个城市(C市、W市、S市)浅层地下水的单环芳烃进行了研究。根据研究区水样分析数据,总结出该地区单环芳烃的污染特点和分布特征,然后从研究区污染源分布、单环芳烃的挥发性、研究区降水以及包气带的防护性能等角度探讨了浅层地下水单环芳烃污染形成的原因。研究表明,该区浅层地下水单环芳烃污染呈点状分布,污染范围不大;浅层地下水单环芳烃污染相对较轻而地表水污染严重。浅层地下水单环芳烃污染特征与研究区工业企业分布、单环芳烃的挥发特性、降水以及研究区包气带防污性能密切相关。浅层地下水单环芳烃污染和工业企业分布具有很好的一致性,有机污染物高浓度的检出点均分布在污染工厂附近,无明显污染源的地段,其浅层地下水水样无有机污染物检出;各检测单环芳烃组分的亨利常数均大于1.01×102 Pa·m3·mol-1,所以挥发作用是其主要迁移机理,苯的柱试验表明,苯溶液浓度从1079.0μg/L降低至6.9μg/L仅需26天;研究区包气带为河湖三角洲沉积相的淤泥质粘土,粘粒含量大,粘土矿物含量也很高,富含有机质,其含量大都在1.0%以上,此类土壤具有高的吸附能力,阻滞了污染物向浅层地下水迁移;降雨时浅层地下水中单环芳烃检出率和检出浓度都较高。4种因素综合,使得研究区浅层地下水单环芳烃呈现污染程度轻、分布零散、污染分布范围小的特点。

       

      Abstract: Abstract:The paper deals with the study of monocyclic aromatic hydrocarbon (MAH) in shallow groundwater in three cities (C, W and S) in an area of the Yangtze River delta. Based on the data of water samples, the authors summarize the contamination features and distribution characteristics of MAH and then discuss the cause of MAH contamination in shallow groundwater in terms of the distribution of contamination sources, MAH volatility, precipitation and anti-pollution performance of the aeration zone in the study area. Study indicates that the MAH contamination in shallow groundwater is of point distribution within a small scope and not so serious, while the MAH contamination in surface water is serious. The characteristics of MAH contamination in shallow groundwater of the study area are closely related to the distribution of factories, volatile features of MAH, precipitation and anti-pollution performance of the aeration zone in the study area. The contamination shows good consistency with the distribution of factories. The detection points of organic pollutants with a high concentration are all distributed near polluted factories, while no organic pollutants have been detected from shallow groundwater samples in places without marked contamination sources. Henry's constants of various MAH components detected are all >1.01×102 Pa·m3·mol-1, so volatilization is its main migration mechanism. The column test of benzene indicates that it only takes 26 days for the concentration of the benzene solution to decrease from 1079.0μg/L to 6.9μg/L. The aeration zone in the study area is composed of sludge clay of fluviolacustrine deltaic facies. It contains plenty of clay granules and clay minerals and is rich in organic matter (>1.0%). Therefore the soils have a high adsorptivity to stop the pollutants from migrating to shallow groundwater. When it rains, both the detected MAH rate and concentration are high. The combination of the above-mentioned four factors makes the shallow groundwater in the study area have the following features: the pollution degree is low, MAH is of sporadic distribution and the pollution scope is small.

       

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