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    有机质在铀成矿过程中作用的实验模拟研究

    Experimental simulation study of the role of organic matter in the formation of uranium deposits

    • 摘要: 提要:沉积型铀矿的形成与有机质存在密切联系。实验模拟研究表明:芳香有机酸在弱酸到弱碱性条件下很容易和铀酰根离子发生配位反应,它能通过羧基上的氧原子以多种配位形式和铀形成配位键。此结果验证了前人的一些结论,并直观地展现了有机质的主要官能团与铀离子在溶液中的一些迁移形式。模拟实验结果也显示了烃类在水热条件下对铀成矿的还原作用,它能将六价铀还原成四价铀而沉淀下来。

       

      Abstract: Abstract:The formation of sedimentary uranium deposits has close relation to organic matter. Experimental simulation study indicates that: aromatic organic acid is very easy to coordinate with uranyl ions under the weakly acid to weakly alkaline conditions and the oxygen atoms of its carboxyl coordinate with uranium atoms in a variety of coordination forms to form coordinate bonds. The results of the experiment simulation validate some previous conclusions and intuitionally exhibit some migration forms of main organic matter functional groups and uranyl ions in solution. The results also show the reduction of hydrocarbon in the formation of uranium deposits under hydrothermal conditions. It can reduce U (Ⅵ) into U (Ⅳ) and deposit the latter.

       

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