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    论内蒙古白云鄂博群和白云鄂博超大型稀土-铌-铁矿床成矿的年代

    A discussion on forming time of the Bayan Obo Group and ore-forming time of the Bayan Obo giant REE-Nb-Fe deposit, Inner Mongolia

    • 摘要: 提要:白云鄂博稀土铌铁矿床具十分独特的地质、地球化学特征,所以多时代成矿是难以置信的。白云鄂博矿床成矿时间势必晚于赋矿白云岩及其下伏地层,而较多的地层古生物证据表明白云鄂博群形成于震旦纪至奥陶纪之间。基于赋矿白云岩是热水沉积形成,碳酸盐脉是同源热液交代变质岩或砂岩等形成的认识,笔者等认为,碳酸盐脉中的锆石可能是变质岩或砂岩中的锆石,它们虽被热液改造,其U-Pb年龄仍可能老于成矿年龄。已报道的白云鄂博矿床Sm-Nd等时线年龄虽然主要集中在1.2~1.6 Ga,但也有多个分别为0.4~0.5 Ga、0.8~0.9 Ga和1.0~1.1 Ga的年龄值。笔者等收集了所有已发表的98件白云鄂博矿床矿石、矿物及碳酸岩墙和上覆板岩的Sm-Nd年龄分析数据,用Isoplot程序计算,发现这些数据,除两件异常外,可以拟合成一条直线,相关系数R=0.96325,求得等时线年龄t=1125.8±32.5 Ma,εNd=-3.02。这一结果表明在1125.8±32.5 Ma白云鄂博Sm-Nd同位素时钟启动,且未再受后来的地质作用扰动,指示成矿作用应晚于或等于1.1 Ga,但地质意义尚待研究。若假定Sm-Nd同位素时钟不易被一般地质作用重置,则可以采信白云鄂博矿床辉钼矿的Re-Os模式年龄(439±8 Ma)或黄铁矿Re-Os等时线年龄(439±86 Ma)为白云鄂博的成矿年龄,这与赋矿地层的古生物化石年代相符。

       

      Abstract: Abstract:Mineralization of the Bayan Obo REE-Nb-Fe ore deposit presents very special geochemical characteristics, suggesting the multi-stage mineralization incredible. The forming age of dolomite as the major ore-bearing stratum must be no later than the mineralization of the Bayan Obo ore deposit. Geological age of Bayan Obo Group has been in dispute in long-term period, and changed many times, but abundant paleontological evidences prove that the age of the Bayan Obo Group is between Sinian and Ordovician. The dolomite is a hydrothermal sedimentary formation and the carbonate veins are formed from hydrothermal replacement of the metamorphic rock or sandstone, and consequently, the zircons from the carbonate veins must be originated from the zircons of metamorphic rock or sandstone. Even though these zircons are reformed by the hydrothermal fluid, it is reasonable that the calculated U-Pb ages of these zircons are older than the ore-forming age. Huge amounts of Sm-Nd isochron ages of the Bayan Obo deposit have been reported. Though they mainly concentrate in the range of 1.2-1.6 Ga, some of them are ~400 Ma, ~800 Ma, and ~1000 Ma, and most of them have large inaccuracy. Considering that the Bayan Obo deposit is formed in a single mineralization period, all the 98 Sm-Nd data from published papers about Bayan Obo are calculated by Isoplot program. 98 data can be synthesized in a straight line(only 2 data are far from the isochron line)with correlation coefficient R= 0.96325, and gield t=1125.8±32.5 Ma(λ=6.54×10-12a-1), εNd=-3.02, which shows that the Sm-Nd isotope clock after the onset of 1125.8±32.5 Ma has never been disturbed by subsequent geological events. Therefore the ore-forming age of the Bayan Obo deposit should be no earlier than 1125.8±32.5 Ma. The molybdenite Re-Os model age and the pyrite Re-Os isochron age of 439 ± 8 Ma and 439 ± 86 Ma respectively, which is consistent with the age of paleomicroplant fossils. Assuming that Sm-Nd isotopic clock is very perseverant and difficult to be reset by general geological events, the ore-forming age of 439 Ma is admissible.

       

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