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    沈阳郊区表层土壤有机氯农药残留特征及风险评价

    Residues and risk assessment of organochlorine pesticides in surface soil of Shenyang suburbs

    • 摘要: 提要:利用GC-ECD 定量测定了沈阳郊区21个表层土壤样品中有机氯农药(OCPs)的含量,并对其残留特征、可能来源及生态风险进行了分析。结果表明,研究区表层土壤中OCPs 的检出率达到95.2%,残留量最高值达到 111.67 ng·g-1,平均值26.91 ng·g-1,其中以六六六(HCHs)和滴滴涕(DDTs)为主。与国内其他城市土壤中OCPs含量相比,沈阳郊区表层土壤HCHs和DDTs残留属于较低水平,但HCB残留属于较高水平。研究区OCPs 的来源解析表明OCPs主要来自环境中的早期残留和近期林丹的使用,六氯苯(HCB)的来源还应包括工业生产。相关性分析说明土壤中总有机碳和水溶盐含量是影响OCPs残留的重要因素。生态风险评价显示表层土壤中DDTs类有机氯农药对该区生物可能仍存在生态风险。

       

      Abstract: Abstract: Organochlorine Pesticides (OCPs) of 21 samples in the surface soils of Shenyang suburbs were determined by gas chromatography with electron capture detector ( GC-ECD ), and the residual characteristics, sources of OCPs and ecological risk were analyzed. The results showed that the detection rate of OCPs reached 95 percent and the total concentrations ranged from being lower than the detection limit to 111.67 ng·g-1 with a mean value of 26.91 ng·g-1. Compared with the soils of other cities in China, the levels of HCHs and DDTs in Shenyang were lower, but HCB were higher, while OCPs were dominated by DDTs and HCHs. The source of OCPs was studied, and the result indicated that OCPs might come from the early residues in the environment or the use of lindane, and the source of HCB should also include industrial production. Correlations between OCPs and physicochemical properties of soil demonstrated that total organic carbon ( TOC ) and soluble salt content strongly influenced the residues of OCPs. Meanwhile, according to the environmental risk assessment, DDTs may still have potential ecological impact on the study area.

       

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