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    湖北金山店大型矽卡岩型铁矿石榴子石原位微区分析及其地质意义

    In situ analysis of garnets from the Jingshandian iron skarn deposit, Hubei Province, and its geological implications

    • 摘要: 提要:本文利用电子探针(EMPA)和激光剥蚀电感耦合等离子体质谱(LA?ICPMS)对湖北金山店大型矽卡岩型铁矿中的石榴子石开展了原位微区分析研究,并探讨其成分变化所蕴含的地质意义。金山店铁矿中的石榴子石可以分为早晚两期:早期石榴子石为钙铝榴石和钙铝榴石?钙铁榴石系列,而晚期石榴子石则主要为钙铁榴石,不同阶段石榴子石成分的变化暗示从早到晚流体氧化性增强。晚期石榴子石相比早期石榴子石富含大离子亲石元素、高场强元素和稀土元素。早期石榴子石中钙铝榴石强烈富集HREE,稀土配分模式为左倾型;而钙铝榴石?钙铁榴石系列则轻重稀土元素分异相对较小。不同的晚期石榴子石样品之间REE含量、δEu和轻重稀土分异程度差异较大,甚至个别石榴子石颗粒不同部位的差异也较大,暗示其形成过程中流体性质发生了剧烈的变化,可能与含膏盐地层的加入有关。石榴子石原位微区分析研究暗示含膏盐地层加入金山店铁矿成矿体系可能具有不均一性和阶段性。

       

      Abstract: Abstract: This paper presents in situ microanalysis data of garnets form the Jinshandian iron skarn deposit, Hubei Province. Studies show that garnets from the Jinshandian iron skarn deposit can be divided into two stages, i.e., early Al-rich garnets mainly with grossular and grossular-andradite series, and late Fe-rich garnets dominated by andradite, with the variation implying the increase of the fluid oxidation. Compared with the early garnets, the late stage are rich in large ion lithophile elements and high field strength elements as well as REE. Early grossular shows typical HREE-enrichment and LREE-depletion features, while smaller fractionation between HREE and LREE characterizes grossular-andradite series. Total REE content, δEu and HREE/LREE fractionation degrees of Fe-rich garnet samples vary from sample to sample, and are even different in different parts of a single garnet grain, suggesting that the process of its formation was not stable, and fluid properties changed greatly, possibly due to the addition of evaporate minerals from the wall rocks. Garnet in situ microanalysis research also suggests that the evaporate minerals added into the Jinshandian skarn system had features of heterogeneity and periodicity.

       

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