Characteristics of trace and rare earth elements in Dongqiyishan fluorite deposit, Inner Mongolia: Indication of ore-forming material sources
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Graphical Abstract
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Abstract
This paper is the result of mineral exploration engineering. Objective The Dongqiyishan fluorite deposit is a super-large fluorite deposit, which is related to alkali feldspar granite in the eastern part of the Beishan metallogenic belt. The orebodies are hosted in alkali feldspar granite, griotte and andesite, which are controlled by the rupture and fracture zones near SN or NE dipping. Methods On the basis of studying the geological characteristics of Dongqiyishan fluorite deposit, carry out the studies of rare earth and trace elements geochemistry of fluorite and wall rocks in the fluorite deposit. Results The results show that the trace elements curves in fluorites are consistent, and obviously enriched in high-temperature elements such as Bi, Cd and Mo relative to the crust values, indicating that these fluorite samples have the characteristics of high temperature mineralization and homology. Fluorites and alkali feldspar granites have similar geochemical characteristics of rare earth. The Y/Ho ratios of 10 fluorite samples are ranging from 21.02 to 28.52, the La/Ho ratios ranging from 3.58 to 15.23. The samples all falling into the hydrothermal region of Tb/La-Tb/Ca diagram, except one close to the sedimentary. The Sm/Nd ratios of fluorites ranging from 0.26 to 0.42, and the Sm/Nd ratios of alkali feldspar granites ranging from 0.26 to 0.42. The δEu vaule ranging from 0.6 to 0.64, and the δCe vaule ranging from 0.89 to 0.94. Conclusions Combined with the geological characteristics of the deposit, It is considered the genetic type of the deposit is medium-high temperature magmatic hydrothermal filled type, which belongs to the tungsten-tin-rare -fluorite metallogenic system related to alkali feldspar granite in the area. The ore-forming fluid of Dongqiyishan fluorite deposit is mainly magmatic hydrothermal. The ore-forming material F mainly comes from the deep alkali feldspar granite body, and the Ca mainly comes from the marble strata.
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