不同赋存状态油裂解条件及油裂解型气源灶的正演和反演研究
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国家重点基础研究发展规划项目(2001CB209100)和中石油中青年创新基金项目(2005)共同资助。


Cracking conditions of oils existing in different modes of occurrence and forward and backward inference of gas source rock kitchen of oil cracking type
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    摘要:

    提要:油裂解型气源灶是一种特殊的气源灶,是优质生烃母质在成气过程中派生出的。烃源岩生成的油主要有3种赋存形式:源内分散状液态烃、源外分散状液态烃和源外富集型液态烃。3种赋存状态液态烃的数量及分配比例受内因和外因多种因素控制,就排油率而言,有机碳含量分别为0.67%、0.62%和10.6%的泥岩、灰岩和油页岩,最大排油率分别为45%、55%和80%。原油与不同介质配样的生气动力学实验表明,不同介质条件下甲烷的生成活化能分布有差异,碳酸盐岩对油裂解条件影响最大,可大大降低其活化能,导致原油裂解热学条件降低,体现为油裂解温度的降低;泥岩次之,砂岩影响最小。碳酸盐岩、泥岩和砂岩对油的催化裂解作用依次减弱,不同介质条件下主生气期对应的Ro值:纯原油1.5%~3.8%;碳酸盐岩中的分散原油1.2%~3.2%;泥岩中的分散原油1.3%~3.4%;砂岩中的分散原油1.4%~3.6%。油裂解型气源灶是一种中间体,可以直观看到的是原生气源灶和由此形成的气藏,而对油裂解型气源灶的赋存形式、分布范围、成气数量和储量规模等问题,只能通过正演和反演的研究去确定且相互映证。正演研究以塔里木盆地中下寒武统为例,原始生油量2 232.24×108t,剩余油量806.21×108t,油裂解气量106.95×1012 m3。反演研究以川东北飞仙关组白云岩中油裂解气为例,圈定的古油藏面积约735 km2,古油藏原油数量45×108t,油裂解气量及油裂解气资源量分别为2.72×1012 m3和1.36×1012 m3。

    Abstract:

    Abstract:The gas source rock kitchen of oil cracking type is a kind of special gas source rock kitchen derived from high-quality hydrocarbon source rocks. The oils generated from source rocks mainly have three modes of occurrence: disperse liquid hydrocarbon inside source rocks, disperse liquid hydrocarbon outside source rocks and concentrated liquid hydrocarbon outside source rocks. The quantities and proportions of the three modes of occurrence of hydrocarbon are controlled by various factors, including internal and external ones. As to the oil expulsion efficiency, the organic carbon contents in mudstone, limestone and oil shale are 0.67%, 0.62% and 10.6% respectively and their maximum oil expulsion efficiencies are 45%, 55% and 80% respectively. The kinetic experiments of cracked gas in different media indicate that the activation energy of methane changes according to the medium conditions. Carbonate rocks have the greatest influence on oil cracking and can significantly reduce the activation energy of cracked gas and the temperatures of oil cracking. Mudstone takes the second place and sandstone has the smallest influence. The corresponding Ro values of main gas-generating periods in different media are as follows: 1.5%-3.8% for pure crude oil, 1.2%-3.2% for disperse oil in carbonate rocks, 1.3%-3.4% for disperse oil in mudstone and 1.4%-3.6% for disperse oil in sandstone. The gas source rock kitchen of oil cracking type is an intermediate and what are visible are the primary gas source kitchen and gas accumulation formed by it. However, the modes of occurrence, distribution scope and amount and resources of gas generated for the gas source rock kitchen of oil cracking type can be only determined and proved through forward and backward inference. Take the Middle-Lower Cambrian in the Tarim basin as an example of forward inference, the original oil-generating quantity is 2 232.24×108 t and the residual oil quantity and oil cracked gas quantity are 806.21×108 t and 106.95×1012 m3 respectively. Take the cracked gas in dolomites of the Feixianguan Formation in the northeastern Sichuan basin as an example of backward inference, the area of the delineated paleo-oil accumulation is approximately 735 km2, the quantity of crude oil is 45×108t, and the quantity and resources of oil cracked gas are 2.72×1012 m3 and 1.36×1012 m3 respectively.

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引用本文

赵文智 王兆云 王红军 汪泽成 张水昌 王 震 张庆春. 不同赋存状态油裂解条件及油裂解型气源灶的正演和反演研究[J]. 中国地质, 2006, 33(5): 952-965.
ZHAO Wen-zhi, WANG Zhao-yun, WANG Hong-jun, WANG Ze-cheng, ZHANG Shui-chang, WANG Zhen, ZHANG Qing-chun. Cracking conditions of oils existing in different modes of occurrence and forward and backward inference of gas source rock kitchen of oil cracking type[J]. Geology in China, 2006, 33(5): 952-965(in Chinese with English abstract).

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